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The pair, who have four children together, were married for 22 years.
The fact that this will be the fourth time that Rita Bean has found herself a wedding hat for her son's big day seems not to have dimmed her enthusiasm.
"Sean is very happy and we are absolutely delighted," she says.
"We have met Georgina, and she is a lovely girl." It is expected that Bean's three daughters - Lorna, 20, Molly, 17 and Evie, nine - will all attend the nuptials. Molly and Lorna, from his second marriage to actress Melanie Hill, will thus be in the unusual position of having attended two of their father's weddings: they were bridesmaids when he embarked on his third marriage to actress Abigail Cruttenden in November 1997.
The "Friends" star and his photographer wife announced their separation in April.
"It is with great love, respect, and friendship that we have decided to take some time apart while we determine the future of our relationship," the couple said in a joint statement.